Innovative multifunctional composites for the protection of cultural heritage objects
InHeritage
PN-III-P2-2.1-PED-2021-0627
(591PED/2022)
As the degradation processes of cultural heritage objects remain inevitable, the continuous development of advanced materials able to counteract specific degradation processes is also necessary. Thus, are needed thorough scientific studies in order to develop tailored formulation, in order to protect, preserve, and restore cultural heritage objects, and this represents a continuous challenge for the scientists, aiming to replace the current rather serendipitous approaches in restoration.
Project goal
The main goal of the project is to develop novel multi-layer composite materials with multiple functions (consolidation, self-cleaning and anti-microbial) applicable for the conservation of different inorganic substrates.
Contracting authority: Executive Unit for Financing Higher Education, Research, Development and Innovation (UEFISCDI)
Implementation period: 29/06/2022-20/09/2024
Budget: 598.795 lei
Project director: Dr. Habil. Radu Claudiu Fierăscu
Coordinator:
National Institute for Research & Development in Chemistry and Petrochemistry – ICECHIM Bucharest
Project director: Dr. Habil. Radu Claudiu Fierăscu
Partner 1:
University POLITEHNICA of Bucharest,
Partner responsible: Dr. Ing. Alina Melinescu
Partner 2:
Partner responsible: Dr. Biol. Lia Mara Dițu
The InHeritage project aims to develop novel multi-layer composite materials with multiple functions (consolidation, self-cleaning and anti-microbial effect), applicable for the conservation of different inorganic substrates. The solutions developed in this project will represent not only an alignment to the international level of research, but also a very important technical solution, innovative at national level, that will contribute to the project sustainability after the implementation period.
Identification and sampling of pilot areas. Development of model substrates.
Implementation period: 29/06/2022 – 31/12/2022
Activities:
Development of multifunctional composites.
Implementation period: 01/01/2023 – 31/12/2023
Activities:
Demonstration of functionality and validation of proposed solutions.
Implementation period: 01/01/2024 – 20/06/2024
Activities:
Summary
Since the degradation processes of cultural heritage objects remain inevitable, the continuous development of advanced materials capable of counteracting the specific degradation processes is necessary. Thus, thorough scientific studies are needed to develop a customized formulation to protect, conserve and restore cultural heritage objects, and this represents a continuous challenge for scientists, aiming to replace current approaches in restoration, which are rather under the specter of serendipity.
The InHeritage project thus aims to develop new multilayer composite materials with multiple functions (consolidation, self-cleaning and antimicrobial effect), applicable for the preservation of various inorganic substrates. The solutions developed in this project will represent not only an alignment with international concerns in the field, but also a very important, innovative technical solution at the national level, which will contribute to the sustainability of the project after the implementation period.
The activities expected to be carried out by the consortium during the first year of implementation were:
The proposed activities were carried out in full, supporting the continuation of the project in 2023. Thus, pilot areas were identified (by signing collaboration agreements with several museum institutions) that were studied to identify the main causes of the degradation of vernacular buildings and monuments. Several types of model substrates were identified, on which consolidation studies were started, using the most suitable recipes, according to the literature study.
The obtained results were disseminated within the scientific community, the results of the dissemination being widely presented on the project website (Romanian version – https://icechim.ro/project/inheritage_ro/, English version – https:// icechim.ro/project/inheritage_en/).
No | Estimated results | Obtained results |
---|---|---|
1 | List of pilot areas (at least three), collaboration agreements, if applicable | The list of pilot areas was developed, and collaboration agreements were signed with five museum units (three presenting representative objectives at the regional level and two presenting representative objectives at the national level). |
2 | Report on the structure and biological contamination of cultural heritage objects | The structure of biological contamination of objects of interest, as well as other sources of degradation, was studied and documented |
3 | At least five substrates model, replicating the original substrates | 7 model substrates (5 artificial and 2 natural) were developed, replicating the original substrates |
4 | Report on the most suitable consolidants for each type of substrate | The possibilities of developing consolidants adapted to various types of substrate have been documented |
5 | At least one ISI paper submitted for publication | An ISI paper has been published |
6 | At least two participations at international scientific events | Six participations at international scientific events were registered |
7 | Filing a patent application | A patent application has been filed |
Summary
Since the degradation processes of cultural heritage objects remain inevitable, the continuous development of advanced materials capable of counteracting the specific degradation processes is necessary. Thus, thorough scientific studies are needed to develop a customized formulation to protect, conserve and restore cultural heritage objects, and this represents a continuous challenge for scientists, aiming to replace current approaches in restoration, which are rather under the specter of serendipity.
The InHeritage project thus aims to develop new multilayer composite materials with multiple functions (consolidation, self-cleaning and antimicrobial effect), applicable for the preservation of various inorganic substrates. The solutions developed in this project will represent not only an alignment with international concerns in the field, but also a very important, innovative technical solution at the national level, which will contribute to the sustainability of the project after the implementation period.
The activities planned to be carried out by the consortium during the second stage of project implementation were:
The proposed activities were carried out in full, supporting the continuation of the project in 2024. Thus, the main performances of the multilayer coatings were defined, the original materials were developed and applied, and their effect on the support materials was evaluated; within the stage, the activity of optimizing the recipes and applying the optimized recipes was also started (activity that will continue, according to the implementation plan, during the remaining period of implementation of the second phase (December 2023), as well as within the activity 3.1 of phase III. A report on the characteristics and performances required of multilayer coatings was elaborated, presented in section 1 of the RST.
In this phase, three ISI papers were published, thirteen participations in international scientific events were registered, the workshop Multifunctional composites for the protection of cultural heritage objects: InHeritage project was organized and the invention patent application A00558/2023 was submitted .
The obtained results were disseminated within the scientific community, the results of the dissemination being widely presented on the project website (Romanian version – https://icechim.ro/project/inheritage_ro/, English version – https:// icechim.ro/project/inheritage_en/).
No | Estimated results | Obtained results |
---|---|---|
1 | Report on the required performance of multilayer coatings | A report on the characteristics and performances required of multilayer coatings was developed |
2 | Report on the development and application of multi-layer coatings | A report on the development and application of multilayer coatings was obtained |
3 | Preliminary report on the effect of multilayer coatings on model substrates | The preliminary report on the effect of multilayer coatings on model substrates was elaborated |
4 | Optimized multilayer coatings (at least one recipe for each type of substrate – materials with high Si and Ca contents, respectively) | Two recipes of multilayer coatings corresponding to the two types of support material were optimized, additionally a third composition was proposed |
5 | At least two ISI paper submitted for publication | Three ISI papers have been published |
6 | At least seven participations at international scientific events | Thirteen participations at international scientific events were registered |
7 | Filing a patent application | Patent application A00558/2023 has been filed |
8 | Organizing a workshop | The workshop Multifunctional composites for the protection of cultural heritage objects: InHeritage project was organized |
Summary
Since the degradation processes of cultural heritage objects remain inevitable, the continuous development of advanced materials capable of counteracting the specific degradation processes is necessary. Thus, thorough scientific studies are needed to develop a customized formulation to protect, conserve and restore cultural heritage objects, and this represents a continuous challenge for scientists, aiming to replace the current approaches in restoration, which are rather under the specter of serendipity.
The InHeritage project thus aims to develop new multilayer composite materials with multiple functions (consolidation, self-cleaning and antimicrobial effect), applicable for the preservation of various inorganic substrates. The solutions developed in this project will represent not only an alignment with international concerns in the field, but also a very important, innovative technical solution at the national level, which will contribute to the sustainability of the project after the implementation period.
The activities planned to be carried out by the consortium during the third stage of project implementation were:
a. Act 3.1 – Evaluation of the results obtained for the optimized recipes. Internal validation of the proposed solution;
b. Act 3.2 – Validation by third parties of the proposed solution;
c. Act 3.3 – Elaboration of technical documentation for technology and products;
d. Act 3.4 – LCA for the proposed multilayer coatings and the evaluation of the toxicity of the coatings;
e. Act 3.5 – Dissemination of the results and the project.
The proposed activities were carried out in full, supporting the successful completion of the project. Thus, the results obtained for the optimized recipes were evaluated, both the internal validation of the proposed solutions and their validation by third parties were carried out, the technical-economic documentation for technologies and products were evaluated and developed, as well as the life cycle analysis for coatings, these being also evaluated from the point of view of toxicity. The brief presentation of the achieved objectives is the subject of this Scientific and Technical Report.
In this phase, two papers were submitted for publication in ISI journals (one published and one accepted for publication), four participations in international scientific events and eleven participations in international invention exhibitions were registered, and a patent application was submitted of invention A00070/2024. Also, two doctoral theses and one master’s thesis were supported through the project.
The obtained results were disseminated within the scientific community, the results of the dissemination being widely presented on the project website (Romanian version – https://icechim.ro/project/inheritage_ro/, English version – https:// icechim.ro/project/inheritage_en/).
No | Estimated results | Obtained results |
---|---|---|
1 | Final report (validation) on the effect of multilayer coatings on model substrates; third party validation report | The internal validation of the coatings was carried out. Third-party validation of the proposed solutions was also carried out |
2 | Technical documentation for the proposed technology; | The technical-economic documentation was made for the proposed products and technologies |
3 | Report – LCA for developed materials | Life cycle assessment was performed for the developed materials as well as toxicological analysis of the developed materials |
4 | At least two ISI papers submitted for publication | Two ISI papers were submitted for publication (one published, one accepted for publication) |
5 | At least one participation in international scientific events | Four participations in international scientific conferences were registered (1 invited lecture, 1 oral presentation, 2 posters) |
6 | Additional indicators | Eleven participations in international invention exhibitions were registered |
7 | Additional indicators | A patent application has been filed |
8 | Additional indicators | Two international project proposals have been submitted, with another international project proposal being prepared |
9 | Additional indicators | Two project proposals were submitted at the national level |
Innovative multifunctional composites for the protection of cultural heritage objects
InHeritage
The InHeritage project makes an innovative contribution to the protection of cultural heritage by developing modern materials that can extend the life of historical monuments and artefacts. Through this initiative, Romanian researchers have created unique solutions aimed at conserving and protecting different materials, such as stone and wood, used in traditional constructions.
Among the main achievements of the project are special materials that can:
These solutions have been successfully tested in the laboratory and received international recognition at exhibitions of inventiveness and innovations. Moreover, the project had an important impact on the training of future researchers, contributing to the training of young specialists who will continue the mission of preserving our cultural heritage.
InHeritage not only protects the past, but also secures the future through innovation and education!
SEM compositional maps of the developed composites
Microscopic images of some biodeteriogens during antimicrobial activity evaluation tests
SEM images of the applied nanocomposite materials
Images from tests evaluating the effects of different compositions on model artifacts (unfired bricks).